I haven't had to remove the front leaf spring bolts on my '89 XJ (yet) but they caused me some grief on my old '95 XJ. That whole Jeep did actually!
It was rough and I replaced all of the floor boards and fabricated my own 2"x6" sliders to replace the rusted out sills. That is a fairly common thing to do. While the floors were out I was able to heat the front spring mounts with my O/A torch just enough to back the bolts out. Fortunately they weren't seized in the metal sleeves of the bushings. I got lucky. I wasn't concerned about the bushings but I was happily surprised that the heat didn't destroy them. It would have been hard to access the threaded part of the frame with a torch from the bottom but it was quite easy from the top with the floors out.
The first pic below shows that area from the interior with the floor out. The centre of the pic shows the bolt and it was easy to get to the threaded boss with my torch. Disregard the new metal, that was one of the slider supports I made.
The second pic shows the same area with the new floor in. The "shiny" part in the middle is a 1/4" plate that I welded in to tie the original uni-body frame rails to the sliders and the above support. I also planned to use it as a base for a roll bar IF I ever put one in (... and I didn't). The key thing though is the small square hole in the middle. My thinking was that if I ever had to get at that bolt again, a "trap door" would make it easy. I made a small cover plate for it and attached it with screws. I don't know if anyone else has done this but it would be easy to do without hacking out your floors.
You're on the right course though. If you can get the bolt out with penetrating oil and brute strength that would be better. I've never used Kroil (never seen it here) but I've had better luck with Liquid Wrench vs. PB Blaster. Most of the problem will be that the bolt is likely seized in the in the metal sleeve of the eye bolt bushing. As you're putting in new springs, you might be just as well to cut the old ones so it's easier to get at the mounts.
Fun eh!?
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