Why do you think it would be physically impossible?
The sprocket can fit on the cam in only 1 position. If the cam and sprocket are made correctly, when the marks on the cam sprocket are lined up with the crank sprocket, #1 has to be at TDC on compression.
While in that position, if you pull the chain and rotate the cam by 180, you'll be in the exact same position as if you just rotated the crank 1 revolution. The mark on the cam sprocket will be 180 from where you started but in relation to the pistons, it's exactly the same as leaving the chain in place and rotating the crank 1 turn.