When I replaced the steering box on my '98 XJ I used a SnapOn pitman are puller, applied copious amounts of Kroil and PB Blaster several days ahead. The day of the removal I used ATF mixed with Acetone which has outstanding creeping capability. Loosened the pitman arm nut, but did not remove the nut, installed the puller and snugged it down, smacked the drive end of the puller with a large ball peen hammer, snugged the puller some more and slowly the pitman arm moved to the end of the shaft.
Once the pitman arm comes off... wire brush the splines and add a dab of anti seize before reinstalling