For Cerakote, they do have a special version of their standard coating called "Piston Coat" that is a low emissivity blend. It only comes in two colors (a sort of dull gold or dull red). As the name implies, it was designed for piston and valve heads. The idea being if you coat those, you reduce heat loss and also slightly improve power/efficiency by keeping more heat in the cylinder.
https://www.cerakote.com/shop/cerakote-coating/V-136/piston-coat-oven-cure
https://www.cerakote.com/shop/cerakote-coating/V-139/titanium-red-piston-coat
I've certainly not tried it on pistons, but I did have my exhaust header coated inside and out as well as the outside of my intake manifold with it. I also had the catalytic converter assembly coated on the exterior.
For the exhaust header and especially the catalytic converters, it definitely cuts down on radiant heat a lot. To the point I can run the engine hard, shut it off, and be able to stick my hand between the catalytic converters for a much longer time. (Still can't touch them of course.)
In terms of heat conduction through the pipe walls, the coating does little in that regard, as would any ceramic coating. However, at the higher temperatures we'd see in the catalytic converter assembly and in the exhaust manifold, radiant heat makes up a substantial fraction of the heat loss.
As for getting the exhaust header internally coated and the intake header externally coated, low emissivity also equals low absorptivity. So inside the exhaust header, radiant heat from the hot gases is more likely to be reflected than absorbed. Likewise, outside the intake manifold, radiant heat is also more likely to be reflected than absorbed.
I don't have any data on my scenario, but one thing to look up that does have a lot of data is Low IR Cerakote for firearms. It's a very similar product, just not quite as heat resistant as Piston Coat. Lots of side by side IR photos of uncoated and coated firearms. Very easy to see the difference.
https://www.cerakote.com/news/62/ce...reduced-weapons-visual-ir-signature-detection