Change all the fluids as you get the chance. Engine oil, coolant, brake fluid, transmission fluid, transfer case fluid, and differential fluid. Especially do the differential fluid if you don't know the history of the vehicle. Any water contamination in there will alter the fluid and accelerate wear. Clutch fluid and power steering fluid are rarely needed to be changed.
Keep an eye out for u-joint and ball joint wear. The u-joints in the front axle shaft are known to go bad eventually. On the front driveshaft (and rear, if you have an aftermarket shaft), grease the centering ball in the double cardan joint. If the double cardan joint fails, it often takes the transfer case with it. I like to keep a set of u-joints and ball joints on hand.
Grease any zerks you have.