Here's my experience within the last week, noting my engine had been running too cold since purchased 6 weeks ago, thus I (wrongly) suspected a 180* t-stat previously had previously been installed;
> Drained enough old coolant and added a quart Thermocure in prep for full flush
> Drove off-pavement and on-pavement prox 150 miles
> Drained, flushed with tap water, drained, blew-out, then 2 cycles distilled water likewise drained / blown-out
> Replaced new hoses, new CTCs, new RobertShaw 195* t-stat and new Mopar t-stat gasket
> Filled engine through heater hose and radiator with Zerex G-05
> Ran engine and topped-off after t-stat opened plus filled reservoir to cold level
No leaks, so thought I was golden - until driving off-pavement next day with same boiling in reservoir as the OP described. Manually burped out some air, then another drive with same boiling phenomenon. I did not drill 1/8" bleed hole in the t-stat, figuring no need with that brand being highly regarded. At that point, still using old Moto Rad radiator cap, so replaced that with the new Mopar cap purchased but hadn't installed. Problem now completely gone with no boiling nor abnormal behavior in the reservoir.
Here's what I think had been happening; the old t-stat (despite being marked 195*) wasn't opening fully, thus never got to 212* boiling temp. With the new RobertShaw 195* t-stat, normal engine temps but the old Moto Rad radiator cap didn't hold 18 psi pressure, thus allowed coolant escape to the reservoir. With the combo of new quality brand t-stat and Mopar cap now in play, problem fixed!