I'll bet good money the booster vacuum valve is malfunctioning and is slightly applying the pushrod into the master. The result of that happening is the replenishment ports get covered. When that happens the fluid can go back into the reservoir when the brakes heat up and expand the fluid so instead they start applying the brakes which heats them up, which expands the fluid more, so on and so forth until all 4 corners lock up hard.
1- let it cool, jack it up and see if the wheels are freed up. If they are, it isn't the calipers and wheel cylinders most likely.
2- if they are still locked up, open a bleed screw and see if that frees things up so the wheel can be turned. If not, that points to the caliper being the problem. (unlikely)
3- if they aren't locked when cool, then pull a caliper and with the engine running, see if the piston can be pushed in. If it can't, that points to the master/booster if the brake light on the dash is off. If it is illuminated with the parking brake off, that points to the combo valve but I'm not sure how that could lock up all four.
What does the estimate involve? Sounds like a shotgun diagnosis so far.